In this chapter, we describe the participants in an organic reaction that covers a reactive agent, a leaving group, and the final product.
We also explain how to use symbols and arrows to depict electron movement and the joining & breaking of bonds.
Most Organic reactions are influenced by electron imbalance. The chapter explains the conducive environment that facilitates these reactions.
Chapter Fundamentals of Organic Reactions Covers-
- Types of Arrows Used in Chemistry
- Curved Arrows in Organic Chemistry- with Examples
- Electrophiles- Introduction, Identification and Reaction
- Formation and Classification of Electrophiles- Neutral and Charged
- Difference between Electrophiles and Lewis Acids
- Nucleophile- Identification and Role in a Reaction
- Types of Nucleophiles- Lone Pair
- Types of Nucleophiles- Pie Bond
- Types of Nucleophiles- Sigma Bond
- Periodic Trend and Order in Nucleophilicity
- Introduction to Reactions Involving Nucleophiles
- Nucleophile Reactions- Aliphatic Displacement type - SN1, SN2
- Nucleophile Reactions- Acyl Displacement type
- Nucleophile reactions- Aromatic Displacement type- Electrophilic, Nucleophilic
- Addition Reactions- Electrophilic, Nucleophilic, and Acyl
- Ambident Nucleophiles- Introduction and Formation
- Ambident Nucleophile - Nature of the Substrate
- Ambident Nucleophile- Influence of the Positive Counter Ions
- Ambident Nucleophile- Effect of Solvent
- Lone Pair - Introduction and Formation
- Physical Properties Affected by the Lone Pair- Shape and Bond Angle
- Physical Properties Affected by the Lone Pair- Hydrogen Bonding
- Physical Properties Affected by the Lone Pair- Polarity and Dipole Moment
- Chemical property affected by the Lone pair- Nucleophilicity
- Leaving Group- Introduction and Nature
- Good and Bad Leaving Group
- Factors Determining Stability of the Leaving Groups- Electronegativity, Size, Resonance Stability
- Using pKa as a Measure of Leaving Group Ability
- Leaving Groups in Displacement Reactions
- Leaving Groups in Elimination Reactions