Skip to main content

Organic Chemistry

How to represent molecules using Lewis dot structures? (With Examples)

The Lewis dot structures are used to show the shared electron pairs between the bonded atoms in the molecule and the lone pairs of electrons if any. The representative structures follow the octet rule wherein the atoms combine by either transfer of electrons (loss or gain) or by sharing of valence electrons in a way that the valence shell of the atoms attains the octet configuration.

The electrons involved are shown as dots. A single bond is made up of two electrons, a double four and a triple bond six. Similarly, an atom can have one, two or three lone pairs of electrons.

Inductive Effect

An atom or group of atoms that can pull the bond electrons towards itself or push the bond electrons from itself and decreasingly transmit the effect along the sigma (σ) bonds of the carbon chain inducing permanent polarization in the molecule. Such an effect is called the Inductive effect.

 

Lucas Reagent

An equimolar (1:1) mixture of a Lewis acid anhydrous ZnCl2 and concentrated HCl- Lucas Reagent, is used to identify and classify unknown alcohol (R-OH) as primary (1o), secondary (2o) or tertiary (3o). The Lucas test is based on the speed at which corresponding insoluble alkyl chlorides (R-Cl) are formed post reaction. The formation of alkyl chlorides solution appears as cloudiness/emulsion, and it is correlated with the reactivity of the alcohol, 3o alcohol being the most and 1o being the least.