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Functional Groups in Organic Chemistry

How to identify a functional group from an IUPAC nomenclature- with three examples

The longest carbon chain is the parent chain containing the principal functional group. 

The principle functional group is always given the highest priority, lowest number (1 before 2, 3, 4...), and assigned as a suffix while writing the nomenclature. Therefore, the numbering of the parent chain always starts from the principal functional group.

What is the priority order in polyfunctional compounds while assigning nomenclature?

IUPAC, an international body engaged in developing standards for naming chemical elements and compounds, has laid several rules known as 'IUPAC rules' to identify a molecule by its parent alkane chain and the functional group. It has assigned various suffixes to identify organic chemistry's commonly seen functional groups.

What does R stand for in organic chemistry structures? Its importance.

Carbon's nondiscriminatory nature to form bonds with itself and other elements has led to a wide variety of small and large organic compounds. Carbon-hydrogen compounds called hydrocarbons are mostly inert; however, carbon with other elements (N, O, S, halogen) form functional groups, the reactive part of the molecule. The functional group part of the molecule is where chemical transformations occur. Some organic compounds can have more than one functional group.

Identify the Functional Isomers of C3H6O- Aldehydes, Ketones and Carboxylic Acids

Question- A and B are two functional isomers of compound C3H6O. On heating with NaOH and I2, Isomer B forms a yellow precipitate of Iodoform whereas Isomer A does not form any precipitate. Write the formulae for A and B.

 

1) Functional Isomers are compounds that have same molecular formula but different functional groups. 

Identify the Organic Compound with Molecular Formula C8H16O2- Aldehydes, Ketones and Carboxylic Acids

An Organic Compound 'A' molecular formula C8H16O2 was hydrolyzed with dilute H2SO4 to give a carboxylic acid 'B' and an alcohol 'C.' Oxidation of 'C' with chromic acid also produced 'B.' On dehydration 'C' gives 1-but-ene. Write the equations for the reaction involved.

1) The first step is find out the Degree of Unsaturation (the number of double bonds or the presence of a ring) in the compound. 

The formula is,