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What is the order of the +I effect?

The +I effect is an electron-donating (or an electron-pushing) inductive effect by an atom or group of atoms relative to Hydrogen. It means that a +I group like methyl (-CH3) will push electrons away from itself more than the hydrogen atom would if it occupied the exact position in the molecule.

The push of electrons is represented with an arrow over the bond, (>) indicating the direction of the electron flow.

 

What do you mean by +I effect with example

 

The +I effect of some of the alkyl group of atoms in the decreasing order to Hydrogen is:

-O‑> -COO-> R3C- > R2CH-, RCH2-> CH3-> D-> H-

Notice how the true electron-donating groups have a formal negative charge (-O‑ and -COO-). Even low electronegative atoms of Si and Mg are electron-donating, and last in order are the alkyl groups. 

Alkyl groups are truly electron-donating and show a +I effect when attached to an unsaturated (alkene, alkyne, aryl) or trivalent Carbon (in carbocations).

If alkyl groups are part of unsaturated systems, the order of +I effect is-

 

Tertiary> secondary> primary > CH3

(CH3)3C->(CH3)2CH-> CH3CH2-> CH3->

t-Butyl        Isopropyl       Ethyl    Methyl

 

Related Reading-

Inductive effect (Free)

Electronegativity (Free)

Difference between primary, secondary, tertiary Carbon (Free)

Electronic Displacement in a covalent bond

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