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Organic Chemistry

Sigma Bond

The single covalent bond is referred to as a sigma bond, denoted by the symbol σ.

The sigma bonds are usually mentioned in valence bond theory to visualize the bond formation between atoms to form polyatomic molecules like H2, CH4, etc., by overlapping their atomic orbitals.

Conformation

The different spatial arrangements organic molecules adopt due to the rotation of the single bond are called conformations. A specific conformation is called a conformer or conformational isomer

Many such conformational isomers are undoubtedly interconvertible by single bond rotations. So, these isomers are simply different rotational (or structural) arrangements of the same molecule.

Unified atomic mass unit

The unit used to describe the mass of an atom is the unified atomic mass unit, symbolized as amu or μ.  

The standard used for measuring the mass of an atom is a 12C atom. Carbon-12 (12C) is an isotope of Carbon with 6 protons, 6 neutrons, and 6 electrons.

The unified atomic mass unit is defined as exactly 1/12 th the mass of one Carbon-12 atom.

Ylide

The ylide is an electrically neutral molecule that has a negative carbon with an unshared electron pair (usually a carbanion) adjacent to a positive heteroatom (typically nitrogen, phosphorus, or sulfur), where both the atoms have full octets (eight electrons in their valence shell). 

The bond between the carbanion and positive heteroatom is best described as a polar covalent bond with significant ionic and double-bond character, depending on the ylide type.