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Organic Chemistry

Resonance

Resonance theory explains various observed properties in a molecule using the electron delocalization concept and multiple Lewis structures, which a single Lewis structure cannot.

A single Lewis structure can only describe some but not all of a molecule's observed properties. Resonance theory is helpful in molecules that can be expressed using several Lewis structures, like Benzene or CO2

Heterolytic Cleavage

Heterolytic cleavage or heterolysis is a chemical reaction in which the bond between two atoms breaks unequally so that the two bond electrons reside with only one atom.

The atom that receives both electrons become an electron-rich negatively charged ion (anion, denoted with a negative sign), and the atom that lost the electrons forms a positively charged ion (cation, denoted with a positive sign).

How do nonpolar molecules interact?

A nonpolar molecule is made of two or more atoms where the electronegativity difference between the atoms is less than 0.5. Therefore, the electron density in the bond is equally distributed, and there is no concentration of electrons on one atom to create a charge separation rendering the molecule essentially without poles or nonpolar. Such nonpolar molecules like H2, CH4, He, etc., will interact using the London dispersion forces without forming any positive or negative pole.