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Organic Chemistry

Lewis Structures

Of all the electrons that form part of an atom, the valence electrons are the only ones that participate when atoms combine to form a bond. In ionic bonding, electrons are transferred (either lost or gained), whereas in covalent bonding, two electrons are shared between the two atoms. Double or triple bonds are formed when atoms share more than one electron pair. The atoms do so to attain the stable octet configuration of 8 electrons in their valence shell.

Methylene – Species and Group

As a reactive species, a methylene refers to an electron-deficient carbene, represented as :CH2

Carbenes are carbon-containing electrophiles that contain only 6 valence electrons instead of the standard eight required for stability. It has an unshared electron pair and two bonds, making it a divalent species, highly unstable, having a fleeting existence. Though classified as electrophiles, methylene species have no formal charge and are neutral.

 

Multimolecular Colloids

On the dissolution of a substance in a dispersion medium, the aggregation of a vast number of atoms or smaller molecules of varying sizes (< 10-9 m) leads to the formation of colloidal particles of the size range 10-9 to 10-6 m.

As the colloidal particles are now made up of many atoms or molecules, it is now called multimolecular colloids.

 

Drawing Organic Structures- Lewis Structures

The first time the use of two dots or a colon (:) to represent two electrons acting as connecting links between the two atoms was proposed by G.N. Lewis in 1916.

In his landmark paper, ‘the atom and the molecules,’ he attempted to draw molecular structures using dots to represent the covalent nature of the chemical bonds, now popularly known as the Lewis structures.

So, a molecule of Cl2 was Cl : Cl, two electrons connecting two Cl atoms.