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Organic Chemistry

Differences between Electrofuge and Electrophile

 

Electrofuge

Electrophile

Definition

Electrofuge is a leaving group that is formed due to the heterolytic breakage of a bond wherein post the clevage, it leaves without the bond pair of electrons, and therefore electron deficient. 

Electrophiles are electron-deficient species that may be neutral or charged because of heterolytic bond cleavage. Still, its primary nature is to attract electrons from other electron-rich counterparts and form a new bond.

Homoatomic molecules

When the atoms combining to form molecules are of the same type, it is a homoatomic molecule. For example, when two Hydrogen atoms (2H) combine under an appropriate reaction condition, a Hydrogen molecule (H2) is formed.

A homoatomic molecule can be diatomic (like elemental hydrogen, H2), triatomic (like ozone, O3), or polyatomic (like sulphur allotrope, S8). 

Octet Rule

Atoms generally form bonding arrangements that give them filled shells of electrons like a noble gas configuration. The stability the atom aims for is that of its nearest noble gas.

For example, Lithium (Z = 3, Electronic Configuration = 1s2, 2s1) of the second row would prefer losing one electron to become Li+ (Z = 3, Electronic Configuration = 1s2) having an electronic arrangement similar to its nearest noble gas Helium (Z = 2, Electronic Configuration = 1s2).