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Organic Chemistry

Which side of an unsymmetrical alkene does the reagent attack and why?

Alkenes are double bonds containing molecules. These double bonds are called pie bonds and are made up of two electrons. Due to the presence of the pie electron cloud, alkenes are electron-rich species and interact with electron-deficient species, the electrophiles. The reaction between alkenes and the electrophiles is an addition reaction.

Pi bond

Once the sigma bonds are formed, any additional electrons in the perpendicular unhybridized p-atomic orbitals engage in side-to-side or lateral overlap to form an additional bond known as the pi bond. The symbol π denotes the pi bond, drawn as an additional line over the sigma bond in the molecular structure.

Electrochemistry

A branch of chemistry that deals with the interconversion of chemical energy and electrical energy taking place via the redox reactions.  

It studies how a spontaneous redox reaction capable of generating chemical energy converts it into electrical energy. Example, Electrochemical cell. 

Or how the use of electrical energy can bring about a non-spontaneous chemical reaction. Example, Electrolytic cell.